ci: remove case_validator.py from ALWAYS_RUN_ALL #6468

Job	Run time
Detect File Changes	9s
Oak Ridge \| Frontier (CCE) (gpu-acc)	49m 36s
Oak Ridge \| Frontier (AMD) (gpu-omp)	1h 33m 39s
Oak Ridge \| Frontier (CCE) (gpu-omp)	59m 47s
Georgia Tech \| Phoenix (NVHPC) (gpu-omp)	2h 33m 58s
Georgia Tech \| Phoenix (NVHPC) (gpu-acc)	55m 10s
Georgia Tech \| Phoenix (NVHPC) (cpu)	45m 48s
	7h 38m 7s

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